Kinetics (six experiments):
 

Determine the temperature coefficient and energy of activation of acid hydrolysis of methyl acetate, using linear least squares calculation.
 

Study the inversion of sucrose in presence of two acids, polarimetrically using Guggenheim plots, and hence determine the relative strengths of the acids.
 

Study the saponification of ethyl acetate by sodium hydroxide and determine the temperature coefficient and energy of activation.
 

Study the autocatalytic reaction between oxalic acid and KMnO₄ and determine the order of the reaction using half-life method
 

Study the mutarotation of glucose in presence of acid by polarimetric method, and investigate the influence of acid strength on the rate of reaction. (Use two conc. of HCl acid, base influence not required)
 

Study the kinetics of oxidation of ethanol by chromium (VI) and hence find the order of the reaction by half-life method.

Conductometry and pH-metry (six experiments):
 

Determine the equivalent conductivity of acetic acid at infinite dilution by Kohlrausch's method (deg. of dissoc. not required.)
 

Determine the strengths of the components of the following mixture by conductometric titration using NaOH solution (standardize the NaOH solution using oxalic acid and phenolphthalein): Hydrochloric acid and Acetic acid
 

Determine the strengths of the components of the following mixture by conductometric titration using NaOH solution (standardize the NaOH solution using oxalic acid and phenolphthalein): Sulphuric acid and Copper sulphate
 

Determine the dissociation constant of acetic acid pH-metrically using Hendersen equation.
 

Determine the strengths of the components of the following mixture by pH-metric titration using NaOH solution (standardize the NaOH solution using oxalic acid and phenolphthalein): Hydrochloric acid and acetic acid
 

Determine the strengths of the components of the following mixture by pH-metric titration using NaOH solution (standardize the NaOH solution using oxalic acid and phenolphthalein): Hydrochloric acid and oxalic acid

Spectrophotometry, Refractometry and Miscellaneous (seven experiments.):
 

Verify Beer's law of spectrophotometry for solutions of varying concentrations of KMnO₄/ K₂Cr₂O₇/ CuSO₄.
 

Determine the composition of the ferric-thiocyanate complex spectrophotometrically by Job's method of continuous variation.
 

Verify the mixture law of refraction for a binary mixture of EITHER (i) ethanol (dehydrated) and butanol OR (ii) methanol and propanol. Construct also an additional calibration curve for refractive index of the mixtures and hence determine the composition of the given unknown binary mixture.
 

Determine the molar mass of the polystyrene sample by viscometric method using toluene as solvent
 

Study the complex formation between cupric ion and ammonia by distribution method using chloroform and determine the composition of the complex
 

Perform theoretical calculations on the internuclear potential energy diagram of hydrogen molecular ion (ground electronic level only) using a list of optimum orbital exponent k, and employing a suitable programmable-calculator software.