Plasma Assisted Removal of H2S and Mercaptans


To the bottom of this page To the welcome page

Air-diluted sulfides (up to 1 % H2S or 0.1 % CH3SH) were processed in powerful gliding electrical discharges at up to 70 m3(n)/h pilot scale. Experiments were performed in one or four-stage reactors at 1 atm. Each stage contains 3 main electrodes and one ignition electrode. These discharges produce a non-thermal plasma, which activates oxidation reactions. Up to 100 % clean-up was obtained at very low energy costs: 1 kWh of injected energy can remove all sulfur from 20 m3(n) of polluted air independently on initial pollutants' concentration in the range from 1 ppm to 1 %. The process uses a very simple water washing column, which saturates with the produced SO2 and captures unprocessed H2S via a wet Claus-like process so that we avoid any SO2 emission and obtain non-toxic elemental Sulfur as the unique product:

3 H2S + 3/2 O2 = 2 H2S + SO2 + H2O = 3S + 3 H2O.
Schematic view
of the GlidArc I reactor
Schematic view
of the washing tower
Schematic view
of the four-stage reactor



To the top of this page To the welcome page

1