THE WEIRD BUBBLE
ideal
choice and henceforth adopted as reference discs. They are readily available and
of the right size, and what is left to do is just some polishing of the rim with
a fine sandpaper. The metal to be tested was placed at the outer edge of the
coin and the voltage measured while the disc was running. Several types of
metals were tested with the aim to find the one giving the highest output. The
result is reported in the table together with the
triboelectric series and the thermoelectric series. The tested metals do not
seem to follow neither of these series although a modest contribution from a
thermoelectric effect is to be expected as the metal under test is bound to
become slightly warmer than the rotating disc. The output terminals were loaded with
a 2200μF
capacitor in parallel with a 4.7KΩ
resistor and the current measurement was taken by connecting directly a digital
meter to the output terminals; the reading is thus comprehensive of the contacts
voltage drop and internal resistance of the instrument.
The voltage is positive and proportional to the relative speed of the disc, no matter which direction is rotated, but also to the pressure applied to the contact being tested. Actually the higher the polishing of the sliding surfaces the higher the pressure required to get the same voltage. A rough surface needs a lower pressure but the internal resistance of the generator is increased.
Eventually it was found that bismuth gave the highest reading. Yet, only a small number of metals and alloys were tested and probably there is a combination of materials that would give a much better performance. For example, it was rather by accident that a chunk of conductive ferrite was available for testing giving the highest negative reading; however the sample had a resistance of a few KΩ, not quite a good conductor and definitely not good for a current generator.
Voltage output was measured for many metals (table 1). The output is purely indicative, as consistency could not be kept across all measurements especially concerning pressure and finish of the surface. They seem to follow their own rule although more accurate measurements might give results closer to the triboelectric series (table 2).
Table 1 Electrofriction series, mV
|
|||||||||||||||||
≈ + 2.4 |
≈ + 1.2 |
≈ + 0.7 |
≈
+ 0.6 |
≈
+ 0.5 |
≈
+ 0.3 |
Reference
|
≈ - 5 |
||||||||||
Bismuth |
Iron Cr-Vsteel Brass Tantalum |
Chrome Tungsten Nickel |
18kt-Gold Rhodium Carbon Stain.steel |
Graphite
Aluminium Lead, copper Gold,
zinc |
Silver |
Nickel-Copper alloy |
conductive ferrite |
||||||||||
|
|||||||||||||||||
Table 2
Triboelectric series
|
|||||||||||||||||
++++++ |
+++++ |
++++ |
+++ |
++ |
+ |
Reference
|
|||||||||||
Lead |
Aluminium |
Iron |
Copper Nickel |
Silver |
Brass Stain.
steel |
Gold |
|||||||||||
|
|||||||||||||||||
Table
3 Thermoelectric series
|
|||||||||||||||||
Bismuth Nickel |
Copper Lead |
Chrome Rhodium |
Gold Silver |
Zinc Aluminium |
Iron Tungsten |
In
order to see how local heating was influencing the output voltage, a test (fig.
2) was
carried out. It was expected that a small positive voltage would develop
due to heating generated by the friction between the metal under test and the
Ni-Cu disc. The experiment partly confirmed this because a similar positive
voltage was indeed produced but only when the sample was heated at a temperature
of about 80-100°C above ambient temperature. The normal heating due to friction
in our generator was measured at only a few degrees above ambient temperature.
The conclusion is that most of the voltage comes from friction and not from the
heating effect, besides, it was also found that the conductive ferrite gave a
positive result when running the experiment of fig. 2 while in the friction
generator it gives a negative voltage. Exactly the opposite happens with
bismuth: in the experiment of fig. 2 it gives a negative voltage but it is
positive in the friction generator. This is rather puzzling and it has not been
investigated further. It must be pointed out that the experiment of fig. 2 does
not follow the thermoelectric series (table 3): here we have that the highest
voltage is obtained by different metals heated at the same temperature, for
example a bismuth-iron junction is most effective while a zinc-aluminium
junction is not. In fig. 2 we have different metals heated at different
temperature, actually, in this experiment, even the same metal but at a
different temperature gives a voltage output.
The
voltage of these devices is usually fairly low and it is not feasible to wire
more units in series, as they will add extra pairs of sliding contacts.
One
solution to the above problem is to have two discs instead of one: with suitable
choice of metals you can double the output. Fig. 3 show how a set of
“complementary” metals, in this case
bismuth and nickel-copper alloy, will give twice the voltage using one single
pair of sliding contacts. The problem of these configurations, and all the ones
using bismuth, is that this metal is rather brittle and it is a pain to cut it
as a round disc, it will just brake apart. The best solution is to cast it using
a suitable form but this is not always feasible and the only other alternative
is to melt it on a flat metal surface and then cut it out using the hot tip of a
soldering iron or chipping it off a bit at the time. Bismuth has a low melting
point, similar to lead, and you can do the casting operation in your kitchen,
using all the proper precautions.
Another way to raise the low voltage is using a transformer but in order to do this you need an AC source and fig. 4 shows a solution: the disc is split in two halves while both contacts, of the same material, are placed at opposite places on the disc. The frequency of operation was 25Hz, and with a 1:100 transformer you get a more useful voltage. A soldering gun transformer was used in this test.
Having
experimented with Faraday homopolar generators in the past, I was interested to
see the influence of the contact material on the performance of these
generators. In fig. 5 there is a classic configuration with a strong gold plated
neodymium magnet. No appreciable difference could be detected when contact A was
copper, aluminium or gold but the difference was clearly detected when contact A
was bismuth. The voltage created by friction by the metal pair gold-bismuth adds
algebraically to the voltage generated by the homopolar effect. In the example
of fig. 5 the voltage generated by friction is +1.5mV and will add in one case
and subtract if you reverse the magnet rotation or polarity. Not every
mechanical configuration will show this effect: when the contacts are symmetric
there is no influence of the material used but it will be evident in case of
asymmetric contacts as in fig. 5.
Contact
A |
North |
South |
Gold |
+4.5 mV |
-4.5 mV |
Bismuth |
+6 mV |
-3 mV |
In all experiments we have seen that the material used is what makes the difference and there are metals or combination thereof that will work better than others; constantan, for example, seemed a better alternative to nickel based coins, but only wires were available for experiments and could not be used as a reference disc. Highly conductive ceramic materials are also interesting and some surprise might come from mercury, easy to find but problematic to use in this application because it is a liquid. It is felt that the best material is going to be some sort of hitherto unknown alloy or superconductive compound with the possibility to have friction without any physical contact, as investigated by some researchers. In the meantime, if you like to experiment with bismuth you may find it in some ammunition shops as it is used occasionally as an alternative to lead shots or order it online by some suitable suppliers such as www.scitoys.com.
Related documents
1) Thermoelectric series - http://www.xyroth-enterprises.co.uk/thermser.htm
2) Triboelectric series - http://www.ece.rochester.edu/~jones/demos/triboseries.html
3) Friction without contact - http://www.aip.org/enews/physnews/2003/split/652-3.html
4)
Di Mario, D. 2001, Faraday's Homopolar Generator, Electronics World, (vol. 107-1786), Highbury Business Communications, Swanley, UK